The root נ-צ-ב carries a meaning that goes beyond simple physical standing: מלבי"ם, הכרמל distinguishes נצב from עמד by explaining that while עמד merely denotes standing as the opposite of sitting or walking, נצב conveys a firm, purposeful positioning — a bracing of oneself in relation to some object or task — and Malbim Beur Hamilot on Yeshayahu 3:13 reinforces this by noting that נצב is used precisely where effort and resolve are required, such as standing before a great person or an adversary, such that every נצב is an עומד but not every עומד is a נצב.
This active, relational sense of נצב is confirmed by several commentators: הכתב והקבלה, בראשית כח יג explains that the root serves to describe a functionally purposeful station — the kind of standing that involves attentiveness and benefit, as in a supervisor overseeing work — and Radak on Bereishit 18:2 similarly reads נצבים עליו as meaning those who stand close to someone in order to serve or attend to them, while רד"ק, שמואל א כב ט further clarifies that נצב על means appointed over, as one commissioned to carry out another's will.
It is against this background that Devarim 29:9 opens the parasha of Nitzavim — אַתֶּם נִצָּבִים הַיּוֹם כֻּלְּכֶם לִפְנֵי יְהֹוָה אֱלֹהֵיכֶם — and Rashi on Devarim 29:9 explains that Moses assembled all Israel before God on the day of his death to bring them into the covenant, while Or HaChaim on Devarim 29:9 reads נצבים here on the model of הַנִּצָּב עַל הַקּוֹצְרִים (Rut 2:5) as a term of appointment and designation, and רש"ר הירש, בראשית כח יג explains that נצב throughout Tanach marks not mere physical standing but a standing of inner alertness and marshaling of one's powers toward something — so the word is profoundly positive.
A מַצֵּבָה, by contrast, is a single upright stone — etymologically sharing the root נ-צ-ב — but defined by its form and function rather than by inner orientation: Rashi on Devarim 12:3 identifies it as a single stone serving as a pedestal for idolatrous worship, and Ramban on Devarim 16:22 distinguishes it from an altar by noting that a מזבח is a multi-stone structure with corners and a base upon which offerings are brought between the horns, whereas a מַצֵּבָה is a single large stone raised for burning incense or offering sacrifices upon it, or for the priests to stand upon.
The Torah's prohibition of the מַצֵּבָה is thus not about the posture of standing but about the idolatrous associations of a single-stone monument: Rashi on Devarim 16:22 states that although the מַצֵּבָה was beloved to God in the days of the Patriarchs — as when Yaakov set one up in Bereishit 28:18 and again in Bereishit 35:14 — God now hates it because the Canaanites made it a fixed ordinance of idolatry, and Sefer HaChinukh 493:1 adds (citing Rambam) that the Torah distances Israel from this practice even if one's intention is to worship God upon it.
The contrast between the single stone and the multiplicity required for Israel's worship carries theological weight: Netivot Olam, Netiv Hadin 1:7 explains that God commanded an altar of many stones because Israel as a nation cleaves to God in His totality and comprehensiveness, whereas a single מַצֵּבָה befits idol worship, which addresses only particular, partial forces — and even the Patriarchs' use of the מַצֵּבָה reflected their individual attachment to a particular divine attribute, something no longer appropriate once Israel became a comprehensive nation, while Kli Yakar on Devarim 16:21 draws the parallel further, noting that just as the altar required many stones rather than a single monument, so the Sanhedrin required many judges, since only the One judges alone.
רש"ר הירש, בראשית כח יח adds a dimension connecting the מַצֵּבָה's material nature to its pre-Sinai legitimacy: the מַצֵּבָה is made from a single stone offered by nature itself, and before the giving of the Torah a person drew God-consciousness from nature and offered back to God nature's own creations — but from Sinai onward the person is obligated to bring to God the work of his own hands, which is why the naturally given single stone no longer suffices.
Igros Moshe (Igros Moshe YD 4:57) rules that a מַצֵּבָה is specifically a single-stone monument erected for sacrificial purposes, and treats Yaakov's act of setting up a single stone at the place where God spoke to him as an example of fulfilling a vow — distinguishing it clearly from a structure built of multiple stones, thereby reinforcing that the prohibition turns on the form of a single stone, not on the concept of upright standing that נצב conveys.